15min:

YAN ZHOU, DAVID GRIMES, ANTHONY COLOMBO AND ROBERT FIELD, Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02319.

Rydberg-Rydberg transitions of Ca atoms are directly detected by chirped-pulse millimeter-wave spectroscopy with broadband, high-resolution spectra with accurate relative intensities. At moderate high number density, the radiation of a Rydberg gas behaves as strong cooperative effects. Compared to a rotational transition, Rydberg-Rydberg transitions have enormous electric dipole transition moments and polarizabilities, which are sensitive to external and self-induced electric fields. In a dense Rydberg gas, a large group of molecules can share an electric field, and absorb and radiate cooperatively. A model with semiclassical method describes several significant cooperative effects in the time-domain and frequency-domain in two-level systems and -type three-level systems. Several experimental evidences which partly support this model will be discussed and a new experiment with buffer gas cooling technique will be proposed.