15min:
OSCILLATOR STRENGTHS AND PREDISSOCIATION RATES FOR RYDBERG COMPLEXES IN 12C16O BETWEEN 92.9 AND 93.4 NM.

M. EIDELSBERG, J. L. LEMAIRE, Observatoire de Paris, Paris, France; S. R. FEDERMAN, Department of Physics and Astronomy, University of Toledo, Toledo, OH 43606; G. STARK, A. N. HEAYS, Department of Physics, Wellesley College, Wellesley, MA 02481; L. GAVILAN, Observatoire de Paris, Paris, France; J. H. FILLION, Université PVI UMPC, Paris, France; F. ROSTAS, Observatoire de Paris, Paris, France; J. R. LYONS, IGPP, University of Califormia, Los Angeles, CA 90095; P. L. SMITH, Department of Physics, Wellesley College, Wellesley, MA 02481; N. DE OLIVEIRA, D. JOYEUX, M. ROUDJANE, L. NAHON, Synchrotron SOLEIL, Saint Aubin, France.

We are conducting experiments on the DESIRS beam-line at the SOLEIL Synchrotron to acquire the necessary data on oscillator strengths and predissociation rates for modeling CO photochemistry in astronomical environments. A VUV Fourier Transform Spectrometer provides a resolving power of about 350,000, allowing us to discern individual lines in electronic transitions. Here we focus on results for six overlapping bands seen in spectra of 12C16O and compare them with earlier determinations. Absorption from the ground electronic level, X 1 Sigma+ v''~=~0, to the upper levels 4p pi(2), II 1 Pi, 4p sigma(2), 5p pi(0), 5p sigma(0), and I 1 Pi was analyzed. Our results are the first to provide data on each band. The spectra also reveal a continuum feature that was modeled, but its identification is not known at the present time.