15min:

CHRISSY J. KNAPP, PAUL L. RASTON AND WOLFGANG JÄGER, Department of Chemistry, University of Alberta, Edmonton, AB, Canada T6G 2G2.

Helium nanodroplets provide a gentle matrix in which to isolate reactive species for spectroscopic investigations. In our ongoing effort to generate radical species in helium nanodroplets, we have recently focused our attention on the highly reactive hydrogen peroxide (H₂O₂) molecule, a potential precursor for the hydroxyl radical. The infrared spectrum of hydrogen peroxide was measured in helium nanodroplets using a cw OPO infrared laser in the OH stretching region. Several rovibrational transitions in the v₅ band of hydrogen peroxide (and HOOD) were recorded and assigned. Intensities, shapes, and assignments of lines will be discussed, as will prospects for the use of hydrogen peroxide in the production of hydroxyl radicals in helium droplets using laser photolysis.