10min:

SOURAV DUTTA, ADEEL ALTAF, JOHN LORENZ, D. S. ELLIOTT AND YONG P. CHEN, Purdue University, West Lafayette, IN 47907.

We present a spectroscopic study of the X^{1 +} and B¹ states of LiRb. LiRb molecules were formed in a heat-pipe oven and spectroscopic measurements of the laser induced fluorescence (LIF) were performed. LIF to the first 45 vibrational levels of the X^{1 +} state (covering more than 98% of the potential well depth) was observed. We also studied the excitation to the B¹ state with high resolution excitation spectroscopy. The values of vibrational, rotational and other spectroscopic constants for both X^{1 +} and B¹ states will be presented in addition to their dissociation energies. Measurements aimed to probe perturbations in the B¹ state due to other nearby states will be discussed. The use of such spectroscopic information in finding efficient photoassociation pathways for the production of ultracold LiRb molecules will also be discussed. This work is supported by the NSF grant number CCF0829918.