15min:

F. LACKNER, M. THEISEN AND W. E. ERNST, Institute of Experimental Physics, Graz University of Technology, Petersgasse 16, A-8010 Graz, Austria.

Rb and Cs atoms on the surface of helium nanodroplets are ionized by applying a monomer selective resonant two-step ionization scheme. We show that in addition to Rb also Cs atoms stay bound on the surface of helium nanodroplets when excited into the n²P_1/2 (Rb: n = 5, Cs: n = 6) state. Rb atoms are selectively excited either to the 5²P_1/2 or to the 5²P_3/2 state and ionized with a pulsed laser. The formation of stable Rb⁺--He_\textrmriptsizen (n < 20) complexes is observed by ionization via the 5²P_3/2 state. Ions with masses of up to several thousand amu have been monitored, which can be explained by an immersion of the single Rb (Cs) ions into the helium nanodroplet upon ionization via the 5²P_1/2 (6²P_1/2) state.