15min:

TOKIO YUKIYA, NOBUO NISHIMIYA, Department of Electronics and Information Technology, Tokyo Polytechnic University, Iiyama 1583, Atsugi City, Kanagawa 243-0297, Japan; ROBERT J. LE ROY, Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada.

Iodine monobromide has been studied in various wavelength regions by researchers using diffraction grating, microwave, and high-resolution laser techniques combined with a Fourier transform spectrometer. Differences in predictions generated from parameters for the A ³ ₁ and X ^{1 +} states obtained from some of these studies show that it can be difficult to make reliable predictions outside the data region, especially if one is using conventional Dunham expansions. In the present work, high resolution absorption and laser excitation data for the X ^{1 +}- A ³ ₁ system of I⁷⁹Br and I⁸¹Br, together with earlier microwave, infrared, and fluorescence progression data, are analyzed using a direct-potential-fit (DPF) procedure to obtain accurate analytic potential energy functions for the two states that provide a compact unified description of all of the available data, as well as realistic predictions for the unobserved levels of this species.