RH. MICROWAVE (ROTATIONAL)

THURSDAY, JUNE 24, 2010 - 1:30pm

Room: 1000 McPHERSON LAB

Chair: THERESA HUET, University of Lille I, Villeneuve, France

RH01 10min1:30

TRANSIENT/PERMANENT CHIRALITY: ROTATIONAL SPECTRA OF THE DIMERS OF ISOPROPANOL.

LUCA EVANGELISTI, FEDERICO PESCI AND WALTHER CAMINATI, Dipartimento di Chimica "G. Ciamician" dell'Università, Via Selmi 2, I-40126 Bologna, Italy.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI]

RH02			15min1:42

TRIPLE RESONANCE FOR A THREE-LEVEL SYSTEM OF A CHIRAL MOLECULE.

EIZI HIROTA, The Graduate University of Advanced Studies, Hayama, Kanagawa 240-0293, Japan.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]

RH03			15min1:59

CHIRALITY OF AND GEAR MOTION IN ISOPROPYL METHYL SULFILE: A FOURIER TRANSFORM MICROWAVE STUDY.

YOSHIYUKI KAWASHIMA, KEISUKE SAKIEDA, Department of Applied Chemistry, Faculty of Engineering, Kanagawa Institute of Technology, Atsugi, Kanagawa 243-0292, JAPAN; AND EIZI HIROTA, The Graduate University for Advanced Studies, Hayama, Kanagawa 240-0193, JAPAN.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]

RH04			15min2:16

CHIRPED-PULSED FTMW SPECTRUM OF 4-FLUOROBENZYL ALCOHOL. STRUCTURE AND TORSIONAL MOTIONS IN THE GROUND ELECTRONIC STATE PHASE.

RYAN G. BIRD AND DAVID W. PRATT, Department of Chemistry, University of Pittsburgh, Pittsburgh, Pa 15213; JUSTIN L. NEILL AND BROOKS H. PATE, Department of Chemistry, University of Virginia, Charlottesville, Va 22904.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]

RH05			15min2:33

A STUDY OF 4,4-DIMETHYLAMINOBEZONITRILE BY CHIRPED-PULSED FOURIER TRANSFORM MICROWAVE SPECTROSCOPY.

RYAN G. BIRD, VALERIE J. ALSTADT AND DAVID W. PRATT, Department of Chemistry, University of Pittsburgh, Pittsburgh, Pa 15213; JUSTIN L. NEILL AND BROOKS H. PATE, Department of Chemistry, University of Virginia, Charlottesville, Va 22904.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]

RH06			15min2:50

CHIRPED-PULSE FOURIER TRANSFORM MICROWAVE SPECTRUM OF THE LOW GLOBAL WARMING POTENTIAL REFRIGERANT ALTERNATIVE, 2,3,3,3-TETRAFLUOROPROPENE.

MARK D. MARSHALL, HELEN O. LEUNG, Department of Chemistry, Amherst College, P.O. Box 5000, Amherst, MA 01002-5000; JOHN S. MUENTER, Department of Chemistry, University of Rochester, Rochester, NY 14627.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI]

RH07			15min3:07

A 480 MHz CHIRPED-PULSE FOURIER-TRANSFORM MICROWAVE SPECTROMETER: CONSTRUCTION AND MEASUREMENT OF THE ROTATIONAL SPECTRA OF DIVINYL SILANE AND 3,3-DIFLUOROPENTANE.

DANIEL A. OBENCHAIN, AMANDA L. STEBER, ASHLEY A. ELLIOTT, REBECCA A. PEEBLES AND SEAN A. PEEBLES, Department of Chemistry, Eastern Illinois University, 600 Lincoln Avenue, Charleston, IL 61920; CHARLES J. WURREY, Department of Chemistry, University of Missouri-Kansas City, Kansas City, MO 64110; GAMIL A. GUIRGIS, Department of Chemistry and Biochemistry, College of Charleston, Charleston, SC 29424.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]

RH08			15min3:24

CHIRPED-PULSE FTMW SPECTRA OF FLUORINATED MOLECULES: 1,1,1-TRIFLUORO-2-BUTANONE AND 3,3,3-TRIFLUOROPROPIONIC ACID.

L. EVANGELISTI, Dipartimento di Chimica "G. Ciamician" dell'Università, Via Selmi 2, I-40126 Bologna, Italy; J. VAN WIJNGAARDEN, Department of Chemistry, University of Manitoba, Winnipeg, MB, Canada R3T 2N2.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI]

INTERMISSION

RH09			15min4:00

MICROWAVE SPECTROSCOPY OF BIS-(TRIFLUOROMETHYL) PEROXIDE, CF₃OOCF₃.

LU KANG, Department of Biology, Chemistry, and Physics, Southern Polytechnic State Univeristy, Marietta, GA 30060; STEWART E. NOVICK, Department of Chemistry, Wesleyan University, Middletown, CT 06457.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]

RH10			15min4:17

MICROWAVE SPECTROSCOPY AND STRUCTURES OF PERFLUOROHEXANE AND 1H-HEPTAFLUOROPROPANE.

JOSEPH A. FOURNIER, ROBERT K. BOHN, Dept. of Chemistry, Univ. of Connecticut, Storrs, CT 06269-3060; JOHN A. MONTGOMERY JR., Dept. of Physics, Univ. of Connecticut, Storrs, CT 06269-3046.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]

RH11			15min4:34

THE SHAPES OF CHLOROPENTAFLUOROACETONE AND 1,3-DICHLOROTETRAFLUOROACETONE IN THE GAS PHASE.

GAUTAM KADIWAR, CHRISTOPHER T. DEWBERRY, GARRY S. GRUBBS II AND STEPHEN A. COOKE, DEPARTMENT OF CHEMISTRY, UNIVERSITY OF NORTH TEXAS, 1155 UNION CIRCLE #305070, DENTON, TX 76203-5017, U.S.A.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]

RH12			15min4:51

ROTATIONAL ANALYSIS OF BANDS IN THE HIGH-RESOLUTION INFRARED SPECTRA OF trans,trans- AND cis,cis-1,4-DIFLUOROBUTADIENE-2-d₁.

NORMAN C. CRAIG, DEACON J. NEMCHICK, CLAY C. EASTERDAY, ETHAN C. GLOR AND DREW F. K. WILLIAMSON, Department of Chemistry and Biochemistry, Oberlin College, Oberlin, OH 44074; THOMAS A. BLAKE AND ROBERT L. SAMS, Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA 99352.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]

RH13			15min5:08

FIRST MICROWAVE TRANSITIONS IN THE ROTATIONAL SPECTRUM OF

₁₇ OF ACETONE ASSIGNED BY MW-MW DOUBLE RESONANCE.

P. GRONER, Department of Chemistry, University of Missouri-Kansas City, Kansas City, MO 64110-2499; M. UNRATH, D. CHRISTEN, Institute of Physical and Theoretical Chemistry, University of Tübingen, D-72076 Tübingen, Germany.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI]

RH14			15min5:25

THE MILLIMETER-WAVE ROTATIONAL SPECTRUM OF PHENYLACETYLENE.

ZBIGNIEW KISIEL, ADAM KRAŚNICKI, Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46, 02-668 Warszawa, Poland.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]

RH15			15min5:42

ROTATIONAL CONSTANTS FOR M-METHYLBENZALDEHYDE: A STUDY IN LOW BARRIER TORSIONAL SPLITTING.

AMANDA J. SHIRAR, KELLY M. HOTOPP, DAVID S. WILCOX, BRIAN C. DIAN, Department of Chemistry, Purdue University, West Lafayette, IN, 47907.

Abstract: [HTML] [GIF] [PS] [PDF] [DVI] Archived Digital Presentation: [PPT] [GIFS]