15min:
PFI-ZEKE SPECTROSCOPY OF Be2O.

I. O. ANTONOV, M. C. HEAVEN, Department of Chemistry, Emory University, Atlanta, GA 30322.

The PFI-ZEKE spectrum of Be2O+ ion was recorded to obtain accurate ionization energy for Be2O and vibrational frequency data for Be2O+. A short progression of the bending mode was observed, which included bands involving odd changes in the vibrational quanta. This observation indicates that the ion and/or the intermediate state used in the excitation process deviate from D_infinityh symmetry.