15min:
STUDYING THE STEREOCHEMISTRY OF NAPROXEN USING ROTATIONALLY RESOLVED ELECTRONIC SPECTROSCOPY. .

JUSTIN W. YOUNG, LEONARDO ALVAREZ-VALTIERRA AND DAVID W. PRATT, Department of Chemistry, University of Pittsburgh, PA 15260.

Many biochemical processes are stereospecific. An example is the physiological response to a drug that depends on its enantiomeric form. Naproxen is a drug which shows this stereo-specific physiological response. To better understand the stereo specificity of chiral substances, we observed the S1 leftarrowS0 transitions of R- and S-naproxen in the gas phase using rotationally resolved electronic spectroscopy. The results will be discussed.