15min:
HIGH PRECISION MID-IR SPECTROSCOPY OF \mathrm12C16O2 NEAR 4.3 \mathrmµ m.

WEI-JO TING, PEI-LING LUO, CHIEH-HSING CHUNG, Dept. of Physics, National Tsing Hua University, Hsinchu, Taiwan 30013, R.O.C; HSHAN-CHEN CHEN, Inst. of Photonics Technologies, National Tsing Hua University, Hsinchu, Taiwan 30013, R.O.C; YU-HUNG LIEN AND JOW-TSONG SHY, Dept. of Physics, National Tsing Hua University, Hsinchu, Taiwan 30013, R.O.C.

We have observed the sub-Doppler saturation spectrum of the \mathrm12C16O2 near 4.3 \mathrmµ m using a mW-level DFG (Difference Frequency Generation) source. The DFG radiation is generated by a 1-W Ti:sapphire laser and a Nd:YAG laser amplified by 10-W fiber amplifier in a 50-mm long PPLN (Periodically Poled Lithium Niobate) crystal. We are able to generate 2 mW DFG power at 4.3 \mathrmµ m. The Nd:YAG laser is frequency-doubled, and frequency stabilized on one \mathrm127I2 hyperfine transition. The Ti:sapphire laser is locked onto the center of \mathrmCO2 transition and its frequency is measured by an OFC (Optical Frequency Comb). In this talk, we will report our recent measurements on the high J 0001 rightarrow 0000 fundamental band transitions and the hot band 0111 rightarrow 0110 transitions. To increase the signal-to-noise ratio of the observed spectra, the \mathrmCO2 absorption cell in heated to a temperature \mathrm> 500\circC.