15min:
FIRST ANALYSIS OF THE nu5 BAND OF DNO3 (DEUTERATED NITRIC ACID) IN THE 11~µm REGION.

J. KOUBEK, Institute of Chemical Technology, Department of Analytical Chemistry, Technická 5,166 28, Praha 6, Czech Republic, and Laboratoire Inter Universitaire des Systemes Atmosphériques, CNRS, Université Paris 12, 61 Av du General de Gaulle, 94010 Créteil Cedex France; A. PERRIN, Laboratoire Inter Universitaire des Systemes Atmosphériques, CNRS, Université Paris 12, 61 Av du General de Gaulle, 94010 Créteil Cedex France; H. BECKERS, H. WILLNER, Anorg. Chemistry, University of Wuppertal, D-42119 Wuppertal, GERMANY.

The infrared spectrum of DNO3 (deuterated nitric acid) was recorded at high resolution (0.0018 cm -1) in the 800 -1400 cm -1 region on the Bruker IFR 120 HR Fourier transform spectrometer of Wuppertal. The analysis of the nu5 A-type band of DNO3 centered at 887.656 cm -1 was performed taking use of the ground state parameters achieved by Drouin et al. . This band is perturbed by several resonances.