15min:

YUXIU LEI AND DONG-SHENG YANG, Department of Chemistry, University of Kentucky, Lexington, KY 40506-0055.

Scandium complexes of p- and m-terphenyls were prepared in laser-vaporization supersonic molecular beams and studied by pulsed field ionization-zero electron kinetic energy photoelectron spectroscopy and density functional theory calculations. Several initial structures with Sc binding at different phenyl rings and bridging carbon bonds were considered in the calculations. A structure with the six-fold Sc binding at the terminal ring of these terphenyls was identified in our experiments. In both complexes, the ground electronic state of the neutral complexes was determined to be ⁴A, and that of the corresponding ion was ³A. For Sc-(p-terphenyl), the adiabatic ionization energy of 38838(6) cm^-1 and a ring bending frequency of 49 cm^-1 was measured for the quartet neutral molecule, and four vibrational frequencies of 354, 309, 77, and 44 cm^-1 were identified for the triplet ion. These ion frequencies were assigned to two metal-ligand stretches, a ring torsion, and a ring bend, respectively. For Sc-(m-terphenyl), the adiabatic ionization energy was measured to be 38290(6) cm^-1, and seven ion vibrational frequencies were determined to be 436, 377, 355, 330, 303, 279, and 46 cm^-1. Similar to the p-terphenyl complex, these ion frequencies were assigned to metal-ligand stretches and ring deformations.