15min:

JOSH J. NEWBY, REBECCA A. PEEBLES AND SEAN A. PEEBLES, Department of Chemistry, Eastern Illinois University, 600 Lincoln Ave., Charleston, IL 61920 USA.

The rotational spectrum of a weakly bound dimer formed between dimethyl ether and OCS has been observed by Fourier-transform microwave spectroscopy. The rotational constants of the normal isotopic species are found to be A = 4069.4106(23) MHz, B = 1431.7413(7) MHz and C = 1074.2925(5) MHz and the dipole moment components are µ_a = 1.3046(25) D and µ_b = 0.8159(35) D. The rotational constants and dipole moment components are consistent with a heavy atom planar structure in which the OCS lies across the C₂ axis of the dimethyl ether (the O=C...O angle is estimated to be about 83^o by ab initio calculation); the oxygen atom of OCS appears to interact with one of the methyl group hydrogen atoms. Isotopic shifts in the spectra of the DME-O¹³CS and DME-OC³⁴S isotopomers have been found to be consistent with this structure. Ab initio optimizations at the MP2/6-311++G(2d,2p) level will be presented and shown to give very good agreement with the rotational constants obtained from experiment.