15min:
PROGRESS IN THE KNOWLEDGE OF C2H2 SPECTROSCOPIC PARAMETERS IN THE IR.

D. JACQUEMART, L. S. ROTHMAN, Harvard-Smithsonian Center for Astrophysics, Atomic and Molecular Physics Division, 60 Garden Street, Cambridge, MA 02138, USA; V. DANA, J.-Y. MANDIN, C. CLAVEAU, A. VALENTIN, Laboratoire de Physique Moléculaire et Applications, CNRS, case courrier 76, Université Pierre-et-Marie-Curie, 75252 Paris Cedex 05, France; L. RÉGALIA-JARLOT, A. BARBE, Groupe de Spectrométrie Moléculaire et Atmosphérique, Université de Reims-Champagne-Ardenne, CNRS, BP 1039, 51687 Reims Cedex, France.

The acetylene molecule is important for atmospheric, planetary, and astrophysics applications. In order to improve the knowledge of C2H2, systematic measurements of line parameters have been performed. Two main spectral regions have been studied in this work. First, in the 13.6-µm region, line intensities were revisited for the nu5 band and determined for some hot bands, allowing us to update the HITRAN database. Second, in the 5-µm region, numerous line parameters, including positions, intensities, self-broadening coefficients, and self-shifting coefficients of lines belonging to 18 bands were measured for the first time. Intensities were also measured for some new lines in the 4.5-µm region, and a good agreement was observed between previous measurements. Concerning the 3-µm region, where two cold bands were already analyzed for positions and intensities, but where the intensities of numerous hot lines are missing in HITRAN, a study is in progress, and preliminary results will be presented.