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GUIQIU ZHANG, A. MEBEL AND YEN-CHU HSU, INSTITUTE OF ATOMIC AND MOLECULAR SCIENCES, ACADEMIA SINICA, P. O. BOX 23-166, TAIPEI 107, TAIWAN, R. O. C..
The C3Ar van der Waals complex has been produced by photolyzing propargyl bromide at 193 nm in a supersonic molecular beam and probed by the laser-induced fluorescence. The spectroscopy of the ground electronic state of this complex was obtained by the wavelength-resolved emission from the à state. In this preliminary report, the observed vibrational levels of the C3Ar complex were assigned based upon our ab initio results calculated at the MP2/aug-cc-pvtz level.