TF. RADICALS AND IONS

TUESDAY, JUNE 13, 2000 - 1:30PM

Room 1009 SMITH LAB

Chair: BOR-CHEN CHANG, National Central University, Chung-Li, Taiwan

TF01 15min1:30
LIF EXCITATION SPECTROSCOPY OF 3-PENTOXY AND TERT -PENTOXY RADICALS .

C. J. WANG, W. DENG, L. G. SHEMESH, M. D. LILIEN, D. R. KATZ AND T. S. DIBBLE, Department of Chemistry, State University of New York, College of Environmental Science and Forestry, Syracuse, NY 13210. .

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TF02 15min1:47
JET-COOLED VIBRONIC SPECTROSCOPY OF VARIOUS ALKOXY RADICALS.

JEFFREY R. ATWELL, CHRISTOPHER C. CARTER, SANDHYA GOPALAKRISHNAN, BRIAN E. APPLEGATE AND TERRY A. MILLER, The Ohio State University, Dept. of Chemistry, Laser Spectroscopy Facility, 120 W. 18th Avenue, Columbus, Ohio 43210.

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TF03 15min2:04
FLASH PYROLYSIS IR LASER JET SPECTROSCOPY OF KETENE DERIVATIVES.

R. J. LIVINGSTONE, Z. LIU AND P. B. DAVIES, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, United Kingdom; N. R. HORE AND D. K. RUSSELL, Department of Chemistry, University of Auckland, Private Bay 92019 Auckland 1, New Zealand.

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TF04 15min2:21
RYDBERG STATES OF ALLYL RADICAL OBSERVED BY ONE- AND TWO-PHOTON RESONANT IONIZATION SPECTROSCOPY.

JEN-CHIEH WU, RUNHUA LI, JIA-LIN CHANG AND YIT-TSONG CHEN, Department of Chemistry, National Taiwan University, Taipei 106, Taiwan, and Institute of Atomic and Molecular Sciences, Academia Sinica, P.O. Box 23-166, Taipei 106, Taiwan.

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TF05 15min2:38
THE ZEKE SPECTRA OF C3H3 and C3H5.

THOMAS GILBERT, INGO FISCHER AND PETER CHEN, Laboratorium f. Organische Chemie, ETH Zurich, CH-8092 Zurich, Switzerland..

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INTERMISSION

TF06 15min3:10
ROVIBRONIC INTERACTIONS AND l-UNCOUPLING IN THE HIGH-RYDBERG STATES OF HCO CONVERGING TO THE (010) STATE OF THE CATION.

ERIC J. ZÜCKERMAN, ROBERT J. FOLTYNOWICZ, JASON D. ROBINSON, HARTMUT G. HEDDERICH AND EDWARD R. GRANT, Department of Chemistry, Purdue University, West Lafayette, Indiana 47906.

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TF07 15min3:27
THE EFFECTS OF INCREASED VIBRATIONAL AMPLITUDE ON ROVIBRONIC INTERACTIONS AND l-UNCOUPLING IN THE HIGH-RYDBERG STATES OF HCO.

ERIC J. ZÜCKERMAN, ROBERT J. FOLTYNOWICZ, JASON D. ROBINSON AND EDWARD R. GRANT, Department of Chemistry, Purdue University, West Lafayette, Indiana 47906.

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TF08 15min3:44
VIBRATIONAL SPECTROSCOPY OF A TRANSIENT SPECIES THROUGH TIME-RESOLVED FOURIER TRANSFORM IR EMISSION SPECTROSCOPY: THE VINYL RADICAL.

L. LETENDRE AND D.-K. LIU, Department of Chemistry, University of Pennsylvania, Philadelphia PA 19104; C. D. PIBEL, Department of Chemistry, American University, 4400 Massachusetts Avenue NW, Washington, DC 20016; J. B. HALPERN, Department of Chemistry, Howard University, Washington, DC 20059; H.-L. DAI, Department of Chemistry, University of Pennsylvania, Philadelphia PA 19104.

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TF09 15min4:01
DETECTION OF TWO ISOMERS OF THE CYANOVINYL RADICAL: H2CCCN AND CHCHCN BY FTMW SPECTROSCOPY.

J. TANG, K. SEIKI, Y. SUMIYOSHI, Y. ENDO, Department of Basic Sciences, The University of Tokyo, Komaba, Tokyo 153-8902, Japan; AND Y. OHSHIMA, Department of Chemistry, Kyoto University, Kyoto 606-8502, Japan.

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TF10 15min4:18
OBTAINING INFORMATION ON JAHN-TELLER ACTIVE SYSTEMS THROUGH ASYMMETRIC ISOTOPIC SUBSTITUTION: CASE OF CHD2O AND CH2DO METHOXY RADICALS.

ILIA J. KALINOVSKI, WAI Y. FAN, X. L. CHEN, C. BRADLEY MOORE, Chemical Sciences Division of the Lawrence Berkeley National Laboratory and Department of Chemistry, UC Berkeley, Berkeley 94720-1460, California, USA.

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TF11 15min4:35
DETECTION AND CHARACTERIZATION OF ALKYL PEROXY RADICALS USING CAVITY RINGDOWN SPECTROSCOPY.

MICHAEL PUSHKARSKY, SERGEY J. ZALYUBOVSKY AND TERRY A. MILLER, The Ohio State University, Dept. of Chemistry, Laser Spectroscopy Facility, 120 W. 18th Avenue, Columbus, Ohio 43210.

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TF12 15min4:52
LABORATORY DETECTION OF A MOLECULAR BAND COINCIDENT WITH THE DIFFUSE INTERSTELLAR BAND AT lambda4428.

C. D. BALL, M. C. MCCARTHY AND P. THADDEUS, Harvard-Smithsonian Center for Astrophysics, Cambridge, MA 02138 and Division of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138.

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TF13 15min5:09
VIBRONIC SPECTROSCOPY OF CHLOROBENZYL RADICALS IN THE VISIBLE REGION.

SANG KUK LEE, SANG YOUL CHAE, Department of Chemistry, Pusan National University, Pusan, 609-735, South Korea.

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