15min:
HIGH-SENSITIVE SUB-MILLIMETER WAVE SPECTROSCOPY OF IONS AND FREE RADICALS.

K. AKAO, H. OKA AND T. AMANO, Institute for Astrophysics and Planetary Sciences, Ibaraki University, Mito 310, Japan.

Sub-millimeter wave spectroscopy in the frequency range of over 500 GHz has not been a territory of easy access. A number of space sub-millimeter wave telescopes are launched or planned, and in view of imminent collaboration between astronomy and laboratory spectroscopy, a sub-millimeter wave spectrometer system has been constructed with Russian made BWOs as radiation sources. Frequency ranges of 570-700 GHz and 770-840 GHz are covered with two BWOs. The sub-millimeter wave frequency is phase-locked to harmonics of a millimeter wave radiation generated by a Gunn oscillator. The sub-millimeter wave harmonic mixer was fabricated in Köln, a similar one used in G. Winnewisser's group.

Unstable molecular species are generated either in an extended negative glow discharge cell or a hollow cathode discharge cell which can be cooled down to -80 \circC. Several stable and unstable molecules such as 12C18O, O2(1Deltag), HN2+ and their isotopes are used for assessing the sensitivity of the system. The sensitivity of our system is found to be about 2× 10-7 with 1 sec time constant and with 1.5 m path length. It corresponds to minimum detectable absorption coefficient of 1.3× 10-9cm-1.