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G. I. PANGILINA, C. BROWN AND T. P. RUSSELL, Naval Research Lab, Chemistry Division, Code 6110, 4555 Overlook Ave, Washington DC 20375, +under Contract with Nova Research Inc..
Aluminum/air chemistry was investigated through time-resolved emission spectroscopy. The reaction was induced with 20 J/cm2 of laser energy with 8 µs duration at 632 nm. Real-time spectra are collected from a single ablation process. Chemical events are monitored for times up to 100 µs duration, and a maximum temporal resolution of 100 ns. Time-resolved emission from electronic transitions of Al, and the vibro-electronic transitions of AlO at 380-600 nm were observed. The time-evolution of the Al doublet at 394/396 nm, and the B - X transitions of AlO from 460-520 nm are obtained. These spectroscopic results are used to monitor changes in the atomic and molecular states in time. Furthermore, decomposition processes associated with pulsed laser heating are inferred. Details of the experimental technique, and its applicability to study other short lived molecules in real time will be presented.