15min:

ROBERT J. MCMAHON, JEFFREY T. DEPINTO, RANDAL A. SEBURG AND JONATHAN A. HODGES, Department of Chemistry, University of Wisconsin, Madison, WI 53706-1396; JOHN F. STANTON, Institute for Theoretical Chemistry, Department of Chemistry and Biochemistry, University of Texas, Austin, TX 78712.

The electronic absorption spectrum of propadienylidene (H₂C=C=C:) ( 1) has been obtained under conditions of argon matrix isolation at 10 K. Calculations of the ground state and the three lowest singlet excited states of 1 using the equation-of-motion coupled-cluster method have been used to interpret the spectrum. The \astate<-\xstate transition is only vibronically allowed, and gives rise to a series of weak absorptions beginning near 717 nm (1.73 eV). The \bstate<-\xstate transition (535 nm, 2.32 eV) and the \cstate<-\xstate transition (259 nm, 4.79 eV) display vibrational progressions associated with C-C stretching vibrations of ca. 1000 \cm and 900 \cm, respectively. The presence of highly-structured visible absorptions in the spectrum and the confirmed presence of propadienylidene and its homologs in the interstellar medium suggest that this family of compounds might be responsible for some of the mysterious diffuse interstellar bands.