FA08 10min11:17
OPTICALLY PUMPED FAR-INFRARED LASERS FROM METHANOL ISOTOPOMERS: 12CD3OH, 12CH3OD, AND 12CH2DOH; NEW LASER LINES AND FREQUENCY MEASUREMENTS.

E. C. C. VASCONCELLOS, S. C. ZERBETTO, Instituto de Fisica Gleb Wataghin, Departamento de Eletronica Quantica, Universidade Estadual de Campinas (UNICAMP), 13083-970, Campinas, SP, Brazil ; L. R. ZINK AND K. M. EVENSON, National Institute of Standards and Technology, Time and Frequency Division, Boulder, CO 80303-3328.

Methanol and ten of its isotopomers have generated over 2000 far-infrared laser lines when pumped by CO2 lasers. We report here 28 new laser lines from the isotopomers 12CD3OH, 12CH3OD, 12CH2DOH along with their frequencies, relative intensities, relative polarizations and pump offsets. An efficient CO2 laser with extended line coverage provided pumping from high J-fundamental, sequence and hot-band CO2 transitions. Many new short-wavelength (below 100 µm) FIR laser transitions were observed.