FA07 10min11:05
NEW LASER LINES AND FREQUENCY MEASUREMENTS OF FULLY DEUTERATED ISOTOPOMERS OF METHANOL.

E. C. C. VASCONCELLOS, S. C. ZERBETTO, Instituto de Fisica Gleb Wataghin, Departamento de Eletronica Quantica, Universidade Estadual de Campinas (UNICAMP), 13083-970, Campinas, SP, Brazil; L. R. ZINK AND K. M. EVENSON, National Institute of Standards and Technology, Time and Frequency Division, Boulder, CO 80303-3328.

We report new far-infrared laser lines generated from two fully deuterated isotopomers of methanol: 12CD3OD and 13CD3OD; five from 12CD3OD and 22 from 13CD3OD, which added to the previously reported far-infrared laser lines in these two molecules sums up to 300. The laser lines were mainly pumped by the 10R (regular) and 10SR (sequence) bands of a cw - CO2 laser. We measured their frequencies, relative intensities, relative polarizations and pump offsets. The laser lines are in the spectral range from 43.697 to 719.426 µm (6 860 664.6 to 416 710.4 MHz).