MG01 10min1:30
THE INFRARED SPECTRUM OF HBO.

P. COLARUSSO, K.-Q. ZHANG AND P. F. BERNATH, Centre for Molecular Beams and Laser Chemistry, University of Waterloo, Waterloo, Ontario, Canada, N2L 3G1.

The free radical HBO was generated in a high-temperature furnace at 1400\circC. The infrared spectra of the two major isotopic species, H11BO and H10BO, were recorded in emission with a Fourier transform spectrometer (Bruker IFS 120HR). The wavenumber range from 400 to 3500 cm-1 was detected at a resolution of 0.01 cm-1. The three fundamental vibrational bands as well as various combination and hot bands have been observed. A vibrational-rotational analysis of the spectra will be presented.