RH'02 15min3:57
THE TORSION-ROTATION SPECTRUM OF D2O2.

J.-M. FLAUD, Laboratoire de Physique Moléculaire et Atmosphériqe, Université Pierre et Marie Curie et CNRS, 4 place Jussieu, Tour 13, 75252 Paris Cedex, France; J. W. JOHNS AND Z. LU, Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, Ontario K1A 0R6, Canada.

The torsion-rotation spectrum of D2O2 has been recorded in the region from 25 to 600 cm-1 at a resolution (1/MOPD) of 0.003~cm-1 using a modified Bomem Fourier transform spectrometer. The aim of the study is to improve the torsional potential of D2O2 and to locate the weak oxygen-oxygen stretching fundamental which should lie amongst the torsional levels. So far, the pairs of torsional levels with n=0, 1 and 2 and one of the levels with n=3 have been analysed with J and K values up to 30 and 11 respectively. The current state of the analysis will be described.