15min:
INTRACAVITY LASER ABSORPTION SPECTROSCOPY OF PLATINUM NITRIDE IN THE NEAR INFRARED.

LEAH C. O'BRIEN, KAITLIN A. WOMACK, Department of Chemistry, Southern Illinois University, Edwardsville, IL 62026-1652; JAMES J. O'BRIEN, SEAN WHITTEMORE, Department of Chemistry, University of Missouri, St Louis, MO 63121-4499.

The (2,0) band of the A2 Sigma- - X2 Pi1/2 electronic transition of PtN has been recorded using intracavity laser absorption spectroscopy. Transitions from 194PtN, 195PtN, and 196PtN isotopologues are observed, as well as the nuclear hyperfine splitting due to 195Pt with I=1/2. The results of the analysis will be presented and compared with ab initio calculations.